Iodine as a mild, efficient, and cost-effective catalyst for the synthesis of thiiranes from oxiranes |
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| Authors: | Jhillu S Yadav Basi V Subba Reddy Sandip Sengupta Manoj K Gupta Gakul Baishya Sukkala J Harshavardhana and Uttam Dash |
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| Institution: | (1) Department of Chemistry, Faculty of Science, Shahid Beheshti University, G. C., Evin, 1983963113 Tehran, Iran;(2) Department of Phytochemistry, Medicinal Plants and Drugs Research Institute, Shahid Beheshti University, G. C., Evin, 1983963113 Tehran, Iran |
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| Abstract: | We developed an efficient protocol for the synthesis of thiiranes from oxiranes using a catalytic amount of molecular iodine.
The notable features of this procedure are mild reaction conditions, high conversions, short reaction times, economic viability
of the reagents, compatibility with various functionalities, and simple experimental/product isolation procedures which make
it a useful and attractive process for the synthesis of a range of thiiranes. |
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