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Composition of the essential oil of Geocaryum cynapioides (Guss.) L. Engstrand
Authors:Niko S Radulovi?  Nevenka D ?ordevi?  Bojan K Zlatkovi?  Radosav M Pali?
Institution:(1) Department of Chemistry, University of Niš, Višegradska 33, 18000 Niš, Serbia;(2) Department of Biology and Ecology, Faculty of Science and Mathematics, University of Niš, Višegradska 33, 18000 Niš, Serbia
Abstract:Volatile constituents from two fresh samples of the subendemic Geocaryum cynapioides (Guss.) L. Engstrand (Apiaceae) obtained by hydrodistillation were analyzed by GC and GC-MS. Forty four and one hundred-twenty three constituents identified in the oils accounted for 98.7 % and 98.4 % of the total oils, respectively. The major component of both oils was (E)-β-farnesene (73.3 % and 57.7 %) while the other major contributors were: (E,E)-α-farnesene (4.8 % and 14.6 %) and trans-sesquisabinene hydrate (12.2 % and 3.0 %). The constituents endo-fenchyl acetate, and three sesquiterpene lactones belonging to the selinane (callitrisin) and guaiane (grilactone and jalcaguaianolide) series, with a rather restricted natural occurrence, were present in only one of the samples (4.7 %, trace amount, 0.1 %, 0.5 %, respectively) and completely absent from the other distinguishing so the two samples. A chemotaxonomic discussion of the results is presented.
Keywords:Geocaryum cynapioides (Guss  ) L  Engstrand  Apiaceae  essential oil composition  (E)-β  -farnesene            trans-sesquisabinene hydrate            endo-fenchyl acetate  grilactone  chemotaxonomy
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