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Polymerization of Methyl Methacrylate with Samarocene Complex Supported on Mesoporous Silica
Authors:Xu Feng NI  Zhi Quan SHEN  Hajime YASUDA Institute of Polymer Science  Zhejiang University  Hangzhou
Affiliation:Xu Feng NI1,Zhi Quan SHEN1*,Hajime YASUDA2 1Institute of Polymer Science,Zhejiang University,Hangzhou 310027 2Department of Applied Chemistry,Faculty of Engineering,Hiroshima University,Higashi-Hiroshima 724,Japan
Abstract:Samarocene complex was supported on a series of mesoporous silica with various pore sizes. Polymerization of methyl methacrylate (MMA) by these catalysts provide highly syndiotactic PMMAs with higher molecular weights compared with those obtained by solution polymerization with homogeneous catalyst system.
Keywords:Mesoporous silica   supported catalyst   samarocene complex.
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