Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes |
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| Authors: | Gilhespy Michelle Lok Martin Baucherel Xavier |
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| Institution: | Johnson Matthey Catalysts, PO Box 1, Belasis Avenue, Billingham, Cleveland, UK TS23 1LB. |
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| Abstract: | PS-TEMPO, a polymer-supported 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)2 and Mn(NO3)2 as co-catalysts. |
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