| 配合物[Co(phen)2(m-chlorobenzoic acid)2·(H2O)]·(H2O)2的水热合成、晶体结构电化学分析 |
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| 引用本文： | 匡云飞,李昶红,李薇,杨颖群.配合物[Co(phen)2(m-chlorobenzoic acid)2·(H2O)]·(H2O)2的水热合成、晶体结构电化学分析[J].无机化学学报,2007,23(3):537-540. |
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| 作者姓名： | 匡云飞 李昶红 李薇 杨颖群 |
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| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,421008
2. 湖南工学院化学化工系,衡阳,421002 |
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| 基金项目： | 湖南省教育厅资助项目;湖南省衡阳市科技局科研项目;衡阳师范学院青年骨干项目 |
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| 摘 要： | The title complex has been synthesized with m-chlorobenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous in the solvent mixture of water and methanol. Crystal data for this complex: triclinic, space group P1, a=0.870 7(3) nm, b=1.284 4(4) nm, c=1.692 9(5) nm; α=75.430(5)°, β=77.562(5)°, γ=86.346(5)°, V=1.789 4(9) nm3, Dc=1.456 g·cm-3, Z=2, F(000)=806. Final GooF=1.065, R1=0.068 4, wR2=0.127 5. The crystal stru-cture shows that the Cobaly ion is coordinated with four nitrogen atoms from two 1,10-phenanthroline molecules and two oxygen atoms from one m-chlorobenzoic acid molecule and one water molecule respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619087.
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| 关 键 词： | 钴(Ⅱ)配合物 晶体结构 电化学性质 |
| 文章编号： | 1001-4861(2007)03-0537-04 |
| 修稿时间： | 2006年10月30 |
Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of the Complex [Co(phen)2(m-chlorobenzoic acid)2·(H2O)]·(H2O)2 |
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| KUANG Yun-Fei,LI Chang-Hong,LI Wei and YANG Ying-Qun.Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of the Complex [Co(phen)2(m-chlorobenzoic acid)2·(H2O)]·(H2O)2[J].Chinese Journal of Inorganic Chemistry,2007,23(3):537-540. |
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| Authors: | KUANG Yun-Fei LI Chang-Hong LI Wei and YANG Ying-Qun |
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| Institution: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 and Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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