| 铜催化碳-杂原子双键不对称硅氢加成反应的研究进展 |
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| 引用本文： | 陈玲珍,彭家建,厉嘉云,白赢,邱化玉,来国桥.铜催化碳-杂原子双键不对称硅氢加成反应的研究进展[J].有机化学,2008,28(5):761-767. |
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| 作者姓名： | 陈玲珍 彭家建 厉嘉云 白赢 邱化玉 来国桥 |
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| 作者单位： | 杭州师范大学有机硅化学及材料技术教育部重点实验室,杭州,310012 |
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| 摘 要： | 总结了近二十年来铜催化碳-杂原子双键不对称硅氢加成的研究近展, 概括了手性铜配合物催化体系催化简单酮﹑α,β-不饱和酮酯和亚胺的不对称硅氢加成, 并阐述了不对称硅氢加成的催化机理.
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| 关 键 词： | 手性铜配合物 不对称硅氢加成 酮类化合物 机理 |
| 收稿时间： | 2007-7-9 |
| 修稿时间： | 2007-9-7 |
Progress in Asymmetric Hydrosilylation of Car-bon-HeteroatomUnsaturated Double Bond Compounds by Copper Catalyst |
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| CHEN,Ling-Zhen,PENG,Jia-Jian,LI,Jia-Yun,BAI,Ying,QIU,Hua-Yu,LAI,Guo-Qiao.Progress in Asymmetric Hydrosilylation of Car-bon-HeteroatomUnsaturated Double Bond Compounds by Copper Catalyst[J].Chinese Journal of Organic Chemistry,2008,28(5):761-767. |
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| Authors: | CHEN Ling-Zhen PENG Jia-Jian LI Jia-Yun BAI Ying QIU Hua-Yu LAI Guo-Qiao |
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| Institution: | (Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012) |
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| Abstract: | The recent advances in asymmetric hydrosilylation of carbon-heteroatom unsaturated double bond compounds by copper catalysts were summarized. The performances of a variety of different substrates which were catalyzed by the combination of copper complexes and chiral ligand were analyzed. The possible mechanisms of asymmetric hydrosilylation were also discussed. |
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| Keywords: | copper complex asymmetric hydrosilylation ketone mechani |
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