Growth,thermal and optical properties of a new nonlinear optical crystal: ZnBi2B2O7 |
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Authors: | Nan Li Peizhen Fu Yicheng Wu Jianxiu Zhang |
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Institution: | 1. Beijing Center for Crystal Research and Development, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;2. Graduate University of Chinese Academy of Sciences, Beijing 100039, China |
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Abstract: | Single crystals of ZnBi2B2O7 (ZBBO) have been successfully grown by the top-seeded growth method from a high-temperature melt. The crystal was colorless and transparent with size of 15×10×5 mm3. The orientation of ZBBO crystal has been discussed. The melting point, molar enthalpy of fusion, and molar entropy of fusion of the crystal were determined to be 964.02 K, 110680.36 J mol−1, and 113.92 J K−1 mol−1, respectively. The transparency range of the crystal extends from 370 to 2100 nm. |
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Keywords: | 81 10 Fq 81 10 Aj 42 70 Mp |
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