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Phase separation phenomenon in MOCVD-grown GaInP epitaxial layers
Authors:Yu-Li Tsai  Ray-Hua Horng  Ming-Chun Tseng  Chia-hao Kuo  Po-Liang Liu  Dong-Sing Wuu  Der-Yuh Lin
Institution:1. Institute of Precision Engineering, National Chung Hsing University, Taichung 402, Taiwan, R.O.C;2. Institute of Electro-Optical and Materials Science, National Formosa University, Yunlin 632, Taiwan, R.O.C;3. Department of Materials Engineering, National Chung Hsing University, Taichung 402, Taiwan, R.O.C;4. Department of Electronic Engineering, National Changhua University of Education, Changhua 500, Taiwan, R.O.C
Abstract:In-rich and Ga-rich GaInP films were intentionally grown on (0 0 1) GaAs substrates by low-pressure MOCVD to investigate the effect of lattice strain on composition. High-resolution X-ray diffraction (HRXRD) measurement showed that a GaInP single layer exhibits a double-diffracted peak phenomenon. Such a double peak represents a composition separation in the grown film, resulting in two absorption cutoff energies in optical absorption analysis. Cross-sectional transmission electron microscopic (TEM) observation confirmed the composition separation in an In-rich GaInP film. Furthermore, the composition separation amount of a Ga-rich GaInP film after substrate removal was found to be ∼0.5%, which reflects the actual effect of lattice strain on composition during growth stage.
Keywords:61  05  cp  68  55  J&minus    78  66  Fd  81  15  Gh
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