Reaction of ruthenium carbonylcarbide cluster Ru6C(CO)17 with nickelocene and pentamethylcyclopentadiene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Reaction of ruthenium carbonylcarbide cluster Ru6C(CO)17 with nickelocene and pentamethylcyclopentadiene

Authors:	V S Kaganovich Z A Kerzina M I Rybinskaya E Kolehmainen

Institution:	(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation

Abstract:	The reaction of cluster Ru₆C(CO)₁₇ (1) with nickelocene is studied. Five CO ligands rather than a metal-ligand crown are substituted for two cyclopentadienyl groups to give a new complex Ru₆C(⁵-Cp)₂(CO)₁₂ (2). The reaction of cluster1 with entamethylcyclopentadiene leads to new complex Ru₆C(-¹⁵-CH₂C₅Me₄)(CO)₁₄ (3) containing the cr-bond CH₂-Ru, along with an ⁵-coordinated cyclopentadienyl ring.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1171–1172, June, 1995.

Keywords:	ruthenium clusters ligands exchange
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