Photolytic transformations of aluminum,gallium, and indium tris(3,6-di-tert-butyl-1,2-semiquinolates) |
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| Authors: | E. V. Ilyakina O. G. Mishchenko A. V. Piskunov S. V. Maslennikov I. V. Spirina Yu. A. Kurskii A. V. Lado |
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| Affiliation: | (1) Research Institute of Chemistry, Lobachevskii Nizhny Novgorod State University, 23/5 pr. Gagarina 23/5, Nizhny Novgorod, 603950, Russia;(2) Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia |
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| Abstract: | The quantum yields of photolytic transformations of aluminum, gallium, and indium tris(3,6-di-tert-butyl-1,2-semiquinolates) in solutions of saturated hydrocarbons were determined. The final products of photodecomposition formed upon irradiation of the compounds with the light of wavelength 313 nm were identified. The kinetic scheme for decomposition of the metal o-semiquinone complexes upon irradiation is suggested. |
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