Pentafluorophenylthiolate derivatives of ruthenium(II), rhodium(I) and palladium(II) |
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| Authors: | Roberto Saleedo Hugo Torrens |
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| Institution: | (1) División de Estudios de Posgrado, Facultad de Química, UNAM, Ciudad Universitaria, México D.F. |
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| Abstract: | Summary The pentafluorophenylthiolate anion C6F5S]– reacts with chloro-bridged binuclear complexes of RuII, RhI and PdII to give the compounds (N-N)(PPh3)2Ru(SC6F5)]2Cl2 (1) (N-N = bipyridine), LRh(SC6F5)]n (L = cycloocta-1,5-diene (2) or norbornadiene (3), n = 2 and L = dicyclopentadiene (4) for which n is probably 4), (PPh3)Pd(SC6F5)Cl]2 (5) and (MeS-CHMeCHMeSMe)Pd(SC6F5), (6).19F n.m.r. spectroscopy shows a variable number of isomers depending on the compound considered. |
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