Mechanism of negative ion formation in low velocity collisions at surfaces

Theoretical calculations using the coupled angular modes (CAM) method have been used to interpret experimental findings related to the scattered oxygen negative ion fraction (O⁻) in collisions of low energy O⁺ with an Al(1 1 0) surface. The increasing O⁻ ion fraction observed experimentally at low O⁺ velocities can be explained in terms of the distance of closest approach Z_c to the Al surface and the specific charge state of the projectile at this distance. Both Z_c and the charge state influence the charge transfer process between the projectile and the surface at low collision energies.