Decomposition of 2-[4-(2-chloro-1,1-dimethylethyl)phenyl]-propan-2-yl hydroperoxide catalyzed by sulfuric acid |
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Authors: | F. Z. Galin N. M. andriyashina T. V. Le Yu. V. Tomilov V. V. Shereshovets |
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Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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Abstract: | The decomposition of 2-[4-(2-chloro-1,1-dimethylethyl)phenyl]propan-2-yl hydroperoxide in acetone catalyzed by H2SO4 affords 4-(2-chloro-1,1-dimethylethyl)phenol. The kinetics of this reaction at 56°C was studied. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1612–1613, August, 1999. |
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Keywords: | 4-(2-chloro-1,1-dimethylethyl)phenol 2-[4-(2-chloro-1,1-dimethylethyl)phenyl]propan-2-yl hydroperoxide acid-catalyzed decomposition |
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