| A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE |
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| 引用本文： | 袁国卿,陈予英,陈荣耀. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. 高分子科学, 1989, 0(3): 219-224 |
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| 作者姓名： | 袁国卿 陈予英 陈荣耀 |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing，Institute of Chemistry，Academia Sinica，Beijing |
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| 基金项目： | This work was supported by a Grant from the National Natural Science Foundation of China |
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| 摘 要： | A series of porous microspheres of linear and ethylene diacrylate (M') cross-linked copolymers of 2-vinylpyridine (V) and methyl acrylate (M) reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex (MVRh and MVM 'Rh). They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid, and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions.
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| 收稿时间： | 1988-05-14 |
A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE |
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| YUAN Guoqing,CHEN Yuying,CHEN Rongyao. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. Chinese Journal of Polymer Science, 1989, 0(3): 219-224 |
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| Authors: | YUAN Guoqing CHEN Yuying CHEN Rongyao |
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| Affiliation: | Institute of Chemistry; Academia Sinica; Beijing |
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| Abstract: | A series of porous microspheres of linear and ethylene diacrylate (M') cross-linked copolymers of 2-vinylpyridine (V) and methyl acrylate (M) reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex (MVRh and MVM 'Rh). They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid, and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions. |
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| Keywords: | Cis-dicarbonylrhodium cationic complexes Copolymer ligands Carbonylation of methanol to acetic acid and acetic anhydride |
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