Electronic theory for the metal-non-metal transition in simple metal alloys |
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Authors: | A ten Bosch J L Morán-López K H Bennemann |
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Institution: | (1) Fachbereich Physik Institut für Theorie der kondensierten Materie, Freie Universität, Arnimallee 3, D-1000 Berlin 33, Germany |
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Abstract: | The metal-non-metal transition in liquid alloys such as Cs1–x
Au
x
and Li1–x
Pb
x
is explained as resulting from concentration dependent electron charge transfer causing short range atomic order and a change from metallic to ionic bonds. Numerical results for the electronic density of states, the electron charge transfer, the free energy of mixing and the volume change are given. |
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Keywords: | |
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