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Cation radical induced cycloaddition reaction between aryl imines and ethyl diazoacetate |
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| Authors: | Congde Huo Chougu SunDongcheng Hu Xiaodong JiaXiaolan Xu Zhongli Liu |
| Institution: | a Key Laboratory of Eco-EnVironment-Related Polymer Materials, Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
| Abstract: | The reaction of ethyl diazoacetate with aryl imines can be initiated by persistent cation radical salt tris(4-bromophenyl)aminium hexachloroantimonate, giving exclusively cis-aziridine carboxylates. |
| Keywords: | Cation radical Ethyl diazoacetate Aryl imines Aziridine carboxylates Cycloaddition |
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