Synthesis of hydrocarbons and alcohols from CO and H2 in the presence of CO-Rh catalysts |
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| Authors: | A. L. Lapidus Z. Novak M. M. Savel'ev B. Lyukke T. Zimmerman S. D. Pirozhkov Kh. É. Manek S. D. Sominskii L. F. Rar |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow;(2) Central Institute of Organic Chemistry, Academy of Sciences of the German Democratic Republic, Berlin |
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| Abstract: | Catalysts of 4.5% Co- 0.1% Rh- 5:10% Cu/TiO2 display high activity in the synthesis from CO and H2 of a mixture of hydrocarbons and alcohols at 250–300°C and pressures of 0.1–6.0 MPa; these catalysts are more selective than traditional Co catalysts with respect to alcohol formation.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1707–1709, August, 1990. |
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