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New potentialities of electrophilic addition in the assembly of polyfunctional compounds from simple precursors |
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| Authors: | Smit W. A. Lazareva M. I. Smolyakova I. P. Caple R. |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) North Dacota University, Grand Forks, North Dacota, USA;(3) University of Minnesota-Duluth, Minnesota, USA |
| Abstract: | A novel methodology of the multicomponent coupling based on the controlled sequence of the kinetically independent electrophilic additions is suggested and its promise as an efficient protocol for the short synthesis of the structurally diverse polyfunctional compounds from simple precursors is demonstrated. |
| Keywords: | multicomponent coupling sequence of AdE reactions cationoid intermediates episulfonium ions thiophanium ions dicobalthexacarbonyl complexes of alkynes Pauson— Khand reaction aldol cross condensation diastereoselectivity vinyl ethers |
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