Synthesis,chemical properties,and crystal structure of 2,4,6,8-tetra(<Emphasis Type="Italic">tert</Emphasis>-butyl)-9-hydroxyphenoxazin-1-one |
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| Authors: | V I Simakov Yu Yu Gorbanev T E Ivakhnenko V G Zaletov K A Lyssenko Z A Starikova E P Ivakhnenko V I Minkin |
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| Institution: | 1.Southern Federal University,Rostov-on-Don,Russian Federation;2.Institute of Physical and Organic Chemistry,Southern Federal University,Rostov-on-Don,Russian Federation;3.A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Moscow,Russian Federation |
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| Abstract: | The reaction of di(tert-butyl) derivatives of pyrocatechol with 2,6-dihydroxyaniline afforded 2,4,6,8-tetra(tert-butyl)-9-hydroxyphenoxazin-1-one. The chemical properties of the reaction product and its ability to form complexes with
metal salts as the tridentate ligand were investigated. The structure of hydroxyphenoxazinone was established by X-ray diffraction. |
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