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Hartree-fock calculations for excited rydberg states
Authors:Martin Jungen
Institution:(1) Physikalisch-Chemisches Institut der Universität Basel, Klingelbergstrasse 80, Basel, Switzerland
Abstract:A method is introduced which allows to compute self-consistent restricted Hartree-Fock wave functions for excited Rydberg configurations. The concepts of reorganization and electron correlation of Rydberg states are discussed. As an illustration Hartree-Fock calculations for the (ls)(nl) Rydberg series of He are presented.
Keywords:Excited states  Correlation  Reorganization  He-atom
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