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| A Cu/Cinchona P,N-ligand system enabled general asymmetric C(sp~3)–C(sp) coupling | |
| 摘 要： | 正Due to the special structural feature and versatile reactivity towards various types of transformations, alkynes have inspired continuous research interest for their generation, incorporation and application in organic synthesis, chemical biology and material science [1]. Notably, since its invention in 1975, the Sonogashira reaction, which efficiently couples aryl halides with aryl or vinyl terminal alkynes via Pd(0)/Cu(I) synergistic catalysis, has proven to be one of the most |
A Cu/Cinchona P,N-ligand system enabled general asymmetric C(sp3)-C(sp) coupling |
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| Li,Xianwei,Li,Chao-Jun. A Cu/Cinchona P,N-ligand system enabled general asymmetric C(sp3)-C(sp) coupling[J]. Science China Chemistry, 2020, 63(6): 751-752. DOI: 10.1007/s11426-020-9698-0 | |
| Authors: | Li Xianwei Li Chao-Jun |
| Affiliation: | 1.Department of Chemistry and FQRNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. W., Montreal, Quebec, H3A 0B8, Canada ;2.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China ; |
| Abstract: | Science China Chemistry - |
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