True square planar [M{N(SePiPr2)2-Se,Se'}2][M = Sn, Se] complexes. An extraordinary geometrical arrangement for well known centers [Sn(II), Se(II) |
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Authors: | Cea-Olivares Raymundo Moya-Cabrera Mónica García-Montalvo Verónica Castro-Blanco Rafael Toscano Rubén A Hernández-Ortega Simón |
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Affiliation: | Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510 DF México. cea@servidor.unam.mx |
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Abstract: | The syntheses and molecular structures of [M{N(SeP(i)Pr2)2-Se,Se'}2][M = Sn(2), Se(3)] are described, these complexes consist of discrete, monomeric molecules featuring MSe4 cores that comprise true square-planar geometries. |
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