|
|||||
|
|
Aerobic oxidative iodination of organic molecules activated by sodium nitrite |
|
| Authors: | Jernej Iskra Stojan Stavber |
| Institution: | a Laboratory of Organic and Bioorganic Chemistry, Department of Physical and Organic Chemistry, ‘Jo?ef Stefan’ Institute, Jamova 39, 1000 Ljubljana, Slovenia b Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ašker?eva 5, 1000 Ljubljana, Slovenia |
| Abstract: | Aerobic oxidative iodination activated by sodium nitrite occurs effectively and selectively with 100% iodine atom economy with air as the oxidant. Silica-supported sulfuric acid was used for the activation of the catalyst and iodination. Thus, I2/NaNO2/air/silica-supported H2SO4 in acetonitrile iodinated aromatics, ketones and aldehydes effectively at ambient temperature. |
| Keywords: | Iodination Halogenation Haloperoxidation Hydrogen peroxide Green chemistry Aerobic halogenation Organo-halogen compounds |
| 本文献已被 ScienceDirect 等数据库收录！ | |