Probing the substrate specificity of the catalytically self-sufficient cytochrome P450 RhF from a Rhodococcus sp |
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| Authors: | Celik Ayhan Roberts Gareth A White John H Chapman Stephen K Turner Nicholas J Flitsch Sabine L |
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| Institution: | School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, UK. |
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| Abstract: | Analysis of the substrate specificity of the self-sufficient cytochrome P450 RhF revealed that the enzyme tends to catalyse the dealkylation of substituted alkyl-aryl ethers with shorter alkyl moieties more readily than equivalent compounds with longer alkyl groups. |
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