Oxidation of carbon black,propene and toluene on highly reducible Co/SBA-15 catalysts |
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Institution: | 1. Department of Chemical Engineering, Faculty of Engineering, University of Balamand, PO Box 100, Tripoli, Lebanon;2. Department of Chemistry, Faculty of Sciences, University of Balamand, PO Box 100, Tripoli, Lebanon;3. Laboratoire de réactivité de surface, CNRS UMR 7197, Université Pierre-et-Marie-Curie, 4, place Jussieu, case courrier 178, 75252 Paris cedex 05, France |
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Abstract: | Different cobalt loadings (3, 6, 12, 24 wt%) were impregnated using the double-solvent technique on SBA-15 calcined at 500 °C presenting a high specific surface area. The impregnated solids were stabilized at 450 °C in the air. The impregnation of cobalt led to the incorporation of cobalt oxide nanoparticles in the mesoporosity of the SBA-15. The cobalt nanoparticles were easily reducible compared to similar solids prepared by different methods. The presence of these nanoparticles enhanced significantly the reactivity of the catalysts in the considered reaction. The addition of more than 12 wt% of cobalt did not enhance the catalytic reactivity due to the deposition of cobalt oxide species on the surface of the support. The cobalt-impregnated solids are efficient in decreasing the oxidation temperature of different probe molecules and are totally selective towards the formation of CO2 and H2O. |
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Keywords: | Cobalt Mesopores Nanoparticles Oxidation SBA-15 Cobalt Mesopores Nanoparticules Oxydation SBA-15 |
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