Time-resolved spectroscopy of natural and synthetic BeO crystals |
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Authors: | V Yu Ivanov V A Pustovarov A V Kruzhalov D S Tausenev and E I Zinin |
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Abstract: | The results of comparative luminescence investigation of natural and synthetic BeO crystals are presented. Time-resolved luminescence
(2.5–8 eV) and luminescence excitation spectra, and the kinetics of glow decay were measured using ultraviolet-vacuum-ultraviolet
(VUV) synchrotron radiation (5–22 eV) or x-radiation (50–620 eV or 3–62 keV) ranges. X-ray and thermostimulated luminescence
of natural BeO crystals were compared to the glow of additively colored synthetic crystals. The characteristic luminescence
of F and F
+ centers was found in natural crystals. In synthetic crystals similar luminescence is observed only after additive or radiation
coloration by virtue of the creation of F
− and F
+ centers on anion vacancies. The defects found in the crystal lattice of a natural BeO crystal testify to the degree of mineral
metamictization of the given deposit. |
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