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苯乙酮、对甲氧基苯甲醛和芳香胺的Mannich反应
引用本文:邹君华,易林.苯乙酮、对甲氧基苯甲醛和芳香胺的Mannich反应[J].西南师范大学学报(自然科学版),1991(1).
作者姓名:邹君华  易林
作者单位:西南师范大学化学系 (邹君华),西南师范大学化学系(易林)
摘    要:苯乙酮与对甲氧基苯甲醛和芳香胺在少量浓盐酸或HCl-EtOH溶液催化下直接进行Mannich反应,用一步法合成了6个相应的Mannich碱,其中有3个是新的有机化合物,产率高达60%~73%.本文还对Mannich碱生成的条件进行了讨论.

关 键 词:Mannich反应  Mannich碱  对甲氧基苯甲醛  芳香胺  苯乙酮

THE MANNICH REACTION AMONG ACETOPHENONE, p-METHOXYBENZALDEHYDE AND ARYIAMINES
Zou Junhua Yi Lin.THE MANNICH REACTION AMONG ACETOPHENONE, p-METHOXYBENZALDEHYDE AND ARYIAMINES[J].Journal of Southwest China Normal University(Natural Science),1991(1).
Authors:Zou Junhua Yi Lin
Institution:Southwest China Teachers Universmty
Abstract:In the presence of catalytic amount of concentrated hydrochloric acid or ethanolic-HCl solution. the Mannich reaction among acetophenone. methoxybenzaldehyde and arylamines was carried out directly to form six corresponding Mannich bases, in which there were three new compounds. The yields were 60%-73 %. The reaction conditions were discussed.
Keywords:Mannich reaction  Mannich bases  p-methoxybenzldehyde  arylamines  acetophenone
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