The relationship between properties of fluorinated graphite intercalates and matrix composition |
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Authors: | D. V. Pinakov V. A. Logvinenko G. N. Chekhova |
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Affiliation: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, Novosibirsk-90, 630090, Russia
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Abstract: | Inclusion compounds (intercalates) of fluorinated graphite matrix with butanone (C2FxBrz·yCH3COC2H5, x = 0.49, 0.69, 0.87, 0.92, z ≈ 0.01) were prepared by guest substitution from acetonitrile to butanone. The kinetics of the thermal decomposition (the 1st stage of filling → the 2nd stage of filling) was studied under isothermal conditions at 294–313 K. The relationship of the host matrices structure with inclusion compounds’ thermal properties and kinetic parameters is discussed. |
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