Deoxygenation of biomass-derived feedstocks: oxorhenium-catalyzed deoxydehydration of sugars and sugar alcohols |
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| Authors: | Mika Shiramizu F Dean Toste |
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| Institution: | Department of Chemistry University of California, Berkeley, Berkeley, CA 94720 (USA). |
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| Abstract: | Turn sugar into oil: The deoxygenation reaction of sugar moieties is important for the conversion of biomass into chemicals and fuels. The methyltrioxorhenium-catalyzed deoxydehydration reaction was successfully applied to this purpose using another alcohol as solvent/reductant. The reaction was highly stereospecific, affording linear polyene products from C(4) -C(6) sugar alcohols and aromatic compounds from C(4) -C(6) sugars. |
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| Keywords: | biomass deoxydehydration deoxygenation rhenium sustainable chemistry |
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