Palladium-catalyzed 1,1-difunctionalization of ethylene |
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Authors: | Vaneet Saini Matthew S Sigman |
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Affiliation: | Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0085, USA. |
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Abstract: | The 1,1-difunctionalization of ethylene, with aryl/vinyl/heteroaryl transmetalating agents and vinyl electrophiles, is reported. The reaction is high-yielding under a low pressure of ethylene, and regioselectivity is generally high for the 1,1-disubstituted product. The process is highlighted by the use of heteroaromatic cross-coupling reagents, which have not been competent reaction partners in previously reported efforts. |
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