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Triterpene Glycosides from Plants of the Astragalus Genus. III. Structure of Cyclounifolioside C from Astragalus unifoliolatus
Authors:K. Dzh. Kucherbaev  K. K. Uteniyazov  V. V. Kachala  Z. Saatov  A. S. Shashkov
Affiliation:(1) S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent;(2) N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Leninskii pr. 47
Abstract:The known compound cyclocantogenin (1) and a new cycloartane glycoside cyclounifolioside C (2), which has the structure 24R-cycloartan-3beta,6agr,16beta,24,25-pentaol 3-O-beta-D-glucopyranoside, were isolated from roots of Astragalus unifoliolatus Bunge. The structures of the isolated compounds are established using hydrolysis and spectral data.
Keywords:Astragalus unifoliolatus  triterpene glycoside  cycloartane  24R-cycloartan-3  /content/p313m74075211794/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >,6  /content/p313m74075211794/xxlarge945.gif"   alt="  agr"   align="  BASELINE"   BORDER="  0"  >,16  /content/p313m74075211794/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >,24,25-pentaol 3-O-  /content/p313m74075211794/xxlarge946.gif"   alt="  beta"   align="  MIDDLE"   BORDER="  0"  >-D-glucopyranoside  cycloasgenin C  cyclocantogenin
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