A fiber-optic cyclodextrin-based sensor |
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Authors: | Alarie J P Vo-Dinh T |
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Affiliation: | Advanced Monitoring Development Group, Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6101, U.S.A. |
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Abstract: | This paper describes the development of a fiber-optic cyclodextrin-based (FCD) sensor. The device uses laser excitation and fluorescence detection with beta-cyclodextrin as the reagent phase, immobilized at the tip of an optical fiber. The sensitivity of the FCD sensor is 14 times as great as that of a bare optical fiber when measurements are made with the fiber immersed in a buffer after a 10-min incubation period. The selectivity of the sensor is illustrated with pyrene as the model compound and 5,6-benzoquinoline as the interferent. An interference study with a contaminated environmental ground water sample is used to illustrate the usefulness of the FCD device. |
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