Influence of graphite furnace tube design on vapour temperatures and chemical interferences in ETA-AAS |
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| Authors: | Ajayi O O Littlejohn D Boss C B |
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| Institution: | Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland. |
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| Abstract: | A two-line atomic absorption method for determination of lead was used for calculation of the temperatures experienced by analyte atoms in the gas phase after wall atomization with modified Philips SP-9 graphite tubes. For each tube, the influence of the temperature gradient on the vapour phase temperature and chemical interferences experienced by Cd, Mn and Pb in ETA-AAS was investigated. A higher vapour temperature and lower chemical interference by chlorides were observed when the tube temperature gradient was reversed through a reduction in the wall thickness towards the ends of the tube. |
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