| 缩聚的溶剂体系对芳香－脂肪族共聚酰胺序列结构的影响 |
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| 引用本文： | 刘德山,谷立广,王晓工,王慧芬,王伟,周其庠. 缩聚的溶剂体系对芳香－脂肪族共聚酰胺序列结构的影响[J]. 高分子学报, 1995, 0(6) |
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| 作者姓名： | 刘德山 谷立广 王晓工 王慧芬 王伟 周其庠 |
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| 作者单位： | 清华大学化学工程系 |
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| 摘 要： | 本文研究了以对苯二甲酰氯、对苯二胺和乙二胺三元共缩聚物为代表的芳－脂族共聚酰胺低温溶液缩聚中的溶剂、助溶剂（盐）和酸吸收剂等对共聚酰胺链序列结构参数－无规度（Ｂ）和数均序列长度（Ｌ）－的影响．
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| 关 键 词： | 芳香－脂肪族共聚酰胺，序列结构，酸吸收剂，酰胺－盐溶剂体系 |
EFFECT OF SOLVENT SYSTEM IN SOLUTION POLYCONDENSATION ON SEQUENCE STRUCTURE OF LYOTROPIC LIQUID CRYSTALLINE AROMATIC-ALIPHATIC COPOLYAMIDES |
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| LIU Deshan, GU Liguang, WANG Xiaogong, WANG Huifen,WANG Wei, ZHOU Qixiang. EFFECT OF SOLVENT SYSTEM IN SOLUTION POLYCONDENSATION ON SEQUENCE STRUCTURE OF LYOTROPIC LIQUID CRYSTALLINE AROMATIC-ALIPHATIC COPOLYAMIDES[J]. Acta Polymerica Sinica, 1995, 0(6) |
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| Authors: | LIU Deshan GU Liguang WANG Xiaogong WANG Huifen WANG Wei ZHOU Qixiang |
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| Abstract: | he aromatic-aliphahc copolyamide based on terephthalyl chloride (TPC), p-phenylenediamine (PPD) and 1, 6-hexanediandne (HDA) was synthesis by low temperature solution copolycondensahon in abide-salt solvent system. The effeCts of the add accepters (AA) and each components of the amide-salt solvent system on the sequence structure, random degree (B) and number average sequence length (Ln), were studied. In order to obtain the aromatic-aliphahc copolyandde with higher B and less Ln, the PKa of AA usually has to be similar to the PKa of diawhnes used as monomers and the g and DN of solventS used should be higher and the amount of the salt used must be reasonable in polycondensahon system. |
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| Keywords: | Aromatic-aliphatic copolyamide Sequence structure Acid accepter Amidesalt solvent system |
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