Intramolecular hydride transfer in the ionic hydrogenation of isopropylcyclopropane |
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Authors: | D. N. Kursanov G. A. Khotimskaya É. I. Fedin M. Yu. Lukina Z. N. Parnes |
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Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR;(2) Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions It was shown that in the ionic hydrogenation of isopropylcyclopropane simultaneously with cleavage of the ring there is an intramolecular hydride transition with the formation of a tertiary carbonium ion, which splits a hydride ion from silane.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 746–748, April, 1969. |
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