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Synthesis and characterization of mixing soft-segmented waterborne polyurethane polymer electrolyte with room temperature ionic liquid
Authors:Yue Jiao Lia  Feng Wu  Ren Jie Chen a School of Chemical Engineering  Environment  Beijing Institute of Technology  Beijing  China b National Development Center for High Technology Green Material  China
Institution:a School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China;b National Development Center for High Technology Green Material, Beijing 100081, China
Abstract:Composite polymer electrolytes based on mixing soft-segment waterborne polyurethane (WPU) and 1-butyl-3-methylimidazolium bis(trifluoromethyl)sulfonyl]imide (BMImTFSI) have been prepared and characterized.The addition of BMImTFSI results in an increase of the ionic conductivity.At high BMImTFSI concentration (BMImTFSI/WPU = 3 in weight ratio),the ionic conductivity reaches 4.27 × 10-3 S/cm at 30 ℃.These composite polymer electrolytes exhibit good thermal and electrochemical stability,which are high enough to be applied in lithium batteries.
Keywords:Composite polymer electrolytes  Ionic liquid  Waterborne polyurethane  Ionic conductivity  1-Butyl-3-methylimidazoliurn bis[(trifluoromethyl)sulfonyl]imide
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