| 黑土长期定位施肥土壤富里酸的荧光特性研究 |
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| 作者姓名： | Li YP Wei D Zhou BK Zhao Y Zhang XL Wei ZM Li SL |
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| 作者单位： | 1. 东北农业大学生命科学学院,黑龙江哈尔滨,150030
2. 黑龙江省农业科学院士壤肥料与环境研究所,黑龙江哈尔滨,150086 |
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| 基金项目： | 国家科技支撑计划课题项目(2006BAD25B05); 黑龙江省杰出青年基金(JC200622); 哈尔滨市创新人才基金项目(2008RFXYN029) |
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| 摘 要： | 选取哈尔滨长期定位施肥对照处理(CK)、施用氮磷钾化肥(NPK)、有机肥马粪(OM)及有机肥与无机肥混施(MNPK)四个不同处理的土壤样品,利用荧光检测技术对土壤富里酸(Fulvic acid,FA)组分进行分析。荧光发射、激发与同步扫描主要特征峰及三维荧光图谱Peak a,b,c均显示:与CK比较,NPK处理均出现明显蓝移,而OM与MNPK出现不同程度红移,表明NPK可使土壤FA结构趋于简单化,OM与MNPK处理则使FA结构趋于复杂。通过对不同处理土壤FA荧光指数f450/500与A1 370~412 nm/A370~600 nm,A4 538~600 nm/A370~600 nm,A4/A1荧光面积积分比值等参数比较分析,进一步说明NPK处理土壤FA芳构化程度较低,而OM与MNPK长期施肥均使FA缩合度与芳构化程度升高。
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| 关 键 词： | 长期培肥 黑土 富里酸 荧光光谱 积分 |
Fluorescence spectroscopic characteristics of fulvic acid from the long-term located fertilization in black soil |
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| Li YP,Wei D,Zhou BK,Zhao Y,Zhang XL,Wei ZM,Li SL.Fluorescence spectroscopic characteristics of fulvic acid from the long-term located fertilization in black soil[J].Spectroscopy and Spectral Analysis,2011,31(10):2758-2762. |
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| Authors: | Li Yan-Ping Wei Dan Zhou Bao-Ku Zhao Yue Zhang Xi-Lin Wei Zi-Min Li Shu-Ling |
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| Institution: | LI Yan-ping1,WEI Dan2,ZHOU Bao-ku2,ZHAO Yue1,ZHANG Xi-lin2,WEI Zi-min1*,LI Shu-ling11.College of Life Science,Northeast Agricultural University,Harbin 150030,China2.Institute of Soil Fertilizer and Environment Research,Heilongjiang Academy of Agriculture Sciences,Harbin 150086,China |
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| Abstract: | In order to investigate the effect of long-term located fertilization on soil fulvic acid(FA),in this study,four soil samples were taken from black soil with long-term located fertilization(about 30 year) in Harbin,Heilongjiang province.The fertilization treatments included control(CK),N,P and K fertilization(NPK),horse manure(OM),combination of organic manure and chemical fertilizations(MNPK).Soil FA was extracted from the samples and purified.The excitation,emission,synchronous,and three-dimensional-excit... |
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| Keywords: | Long-term located fertilization Black soil Fulvic acid Fluorescence spectrum Integration |
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