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The role of metal-oxygen intermediates in biological and chemical monooxygenation of alkanes |
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| Authors: | Shteinman A A |
| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
| Abstract: | The role of metal-peroxo, -hydroperoxo, and -oxo intermediates in activation of O2 and transfer of an oxygen atom to the C—H bond in biocatalysis by heme and non-heme monooxygenases and biomimetic oxidation of alkanes is reviewed. |
| Keywords: | cytochrome P450 methane monooxygenase mechanism metal-oxygen intermediates monooxygenation of alkanes hydroxylation of alkanes biomimetic catalysis ferryl oxygen transfer iron complexes |
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