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测定电位滴定终点的神经网络法
引用本文:蔡煜东,吴伟,甘骏人,姚林声.测定电位滴定终点的神经网络法[J].分析化学,1993(4).
作者姓名:蔡煜东  吴伟  甘骏人  姚林声
作者单位:中国科学院上海冶金研究所,中国科学院上海冶金研究所,中国科学院上海冶金研究所,中国科学院上海冶金研究所 上海 200050,上海 200050,上海 200050,上海 200050
摘    要:本文利用改进的“反向传播”神经网络模型,在滴定突跃附近,建立了E-V曲线的神经网络插值模型,由其二阶微商求得滴定终点。计算实例中,拟合最大相对误差不超过0.1%,计算机CPU时间不超过20s,实验结果表明,该方法性能良好,在电容量分析方面有广阔的应用前景。

关 键 词:电位滴定终点  人工神经网络  反向传播模型二阶微商

Determination of Potential Titration End-point by Neural Network
Cai Yudong,Wu Wei,Gan Junren,Yao Linsheng.Determination of Potential Titration End-point by Neural Network[J].Chinese Journal of Analytical Chemistry,1993(4).
Authors:Cai Yudong  Wu Wei  Gan Junren  Yao Linsheng
Abstract:The approximation model for E-Vcurve near titration steep is constructed by an improved back-propagation neural network model. By calculating the second order derivative of the constructed model, titration end-point is determined. In our examples, the maximum fitting relative error does not exceed 0.1% and the total calculating time does not exceed 20 s. The experimental results show that the neural network is good,and it might be widely used in electro-volumetric analysis.
Keywords:Potential titration end-point  Artificial neural network  Improved back-propagation model  Second order derivative    
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