Kinetics and selectivity of the oxidation of alkanes in Cl2?H2O and Cl2?Hg2+?H2O solutions |
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| Authors: | E S Rudakov L K Volkova and V P Tretiakov |
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| Institution: | (1) Institute of Physical Organic and Carbon Chemistry, Donetsk, USSR |
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| Abstract: | Relative oxidation rate constants of several normal, iso-, cyclo-and methylcycloalkanes have been measured in Cl2–H2O and Cl2–Hg2+–H2O solutions at 343K. The selectivity of C–H bond dissociation in both systems is the same. HOCl is assumed to be the active species for the two systems.
        Cl2–H2O  Cl2–Hg2+–H2O  343            , -, - ;  C–H  .    ,  HOCl.
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