| Synthesis and Characterization of Ferrocenyl Substituted Styryl Octasilsesquioxane |
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| 作者姓名： | Xiao Yan SONG Hai Ping GENG Qi Fang LI |
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| 作者单位： | Xiao Yan SONG，Hai Ping GENG，Qi Fang LI College of material science and engineering，Beijing University of Chemical Technology，Beijing 100029 |
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| 摘 要： | 4-(2-Ferrocenylethenyl)-phenyl-POSS Fc-CH=CH-C6H6-(C5H9)7Si8O12 (FEPS, Fc: ferrocene), containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemical structure of FEPS was characterized by FTIR, 1H-, 13Cand 29Si-NMR.
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| 关 键 词： | 合成 结构表征 二茂铁基 苯乙烯基 八硅倍半氧烷 二茂铁 Wittig反应 |
| 收稿时间： | 2005-09-01 |
Synthesis and Characterization of Ferrocenyl Substituted Styryl Octasilsesquioxane |
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| Xiao Yan SONG Hai Ping GENG Qi Fang LI.Synthesis and Characterization of Ferrocenyl Substituted Styryl Octasilsesquioxane[J].Chinese Chemical Letters,2006,17(4):427-430. |
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| Authors: | Xiao Yan SONG Hai Ping GENG Qi Fang LI |
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| Abstract: | 4-(2-Ferrocenylethenyl)-phenyl-POSS Fc-CH=CH-C6H6-(C5H9)7Si8O12 (FEPS, Fc: ferrocene), containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemical structure of FEPS was characterized by FTIR, 1H-, 13Cand 29Si-NMR. |
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| Keywords: | Polyhedral silsesquioxane ferrocene Wittig reaction synthesis |
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