Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: structural characterization of potassium, calcium, and mixed potassium-calcium enolates |
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Authors: | He Xuyang Noll Bruce C Beatty Alicia Mulvey Robert E Henderson Kenneth W |
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Institution: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA. |
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Abstract: | Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized. |
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