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Lanthanide complexes embedded in silicone resin as a spectral converter for solar cells
Authors:Jae Hyun Han  Sung-Hwan Lee  Byeong-Kwon Ju  Bok-Ryul Yoo  So-Hye Cho  Joon Soo Han
Affiliation:1.Materials Architecturing Research Center,Korea Institute of Science and Technology,Seoul,Republic of Korea;2.Display and Nanosystem Laboratory, College of Engineering,Korea University,Seoul,Republic of Korea;3.Department of Chemistry,Hannam University,Daejeon,Republic of Korea;4.Division of Nano & Information Technology,Korea University of Science and Technology,Daejeon,Republic of Korea
Abstract:The performance of solar cell devices is dependent on various factors, and the spectral mismatch limits the upper limit of performance. Using a spectral converter to manipulate solar radiation is one way to improve solar cell efficiency. We present herein a spectral converter to move the short-wavelength (< 400 nm) range of solar radiation to the longer-wavelength range. The spectral converter comprises fluorescent lanthanide complexes uniformly embedded in silicone resin. A successful spectral converter showed transmittance of over 85%, and when applied in a Si solar cell, its relative efficiency was increased up to 4%.
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