Synthesis of novel perfluoroalkyl ether derivatives |
| |
Authors: | Xiang Shi Hongxin Shi Hongke Wu HaiMin Shen |
| |
Affiliation: | 1.School of Chemical Engineering,Zhejiang University of Technology,Hangzhou,China |
| |
Abstract: | A series of novel fluoroether-containing monomers has been designed and prepared based on the commercially available perfluoroalkyl ether acid fluoride. Treating acid fluoride with allyl alcohol, 2-hydroxyethyl methacrylate or N-allylmethylamine allowed for the direct formation of corresponding vinyl-containing fluorinated monomers. High yields of the fluorinated epoxy monomers could be obtained from acid chloride with glycidol; meanwhile, fluorinated diol was prepared from diethanolamine or 3-amino-1,2-propanediol. Moreover, fluorinated monoamine, fluorinated monoalcohol and fluorinated dichloride were also obtained. Most of these fluorinated monomers were liquid at room temperature and exhibited good solubility in common organic solvents. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|