Synthesis and crystal structure of [Cr(NH<Subscript>3</Subscript>)<Subscript>5</Subscript>Cl][PdBr<Subscript>4</Subscript>]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis and crystal structure of [Cr(NH3)5Cl][PdBr4]

Authors:	A. V. Zadesenets A. B. Venediktov S. V. Korenev I. A. Baidina S. A. Gromilov

Affiliation:	(1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

Abstract:	A new binary complex salt — chloropentaamminechromium(III) tetrabromopalladate(II) [Cr(NH₃)₅Cl][PdBr₄] — has been synthesized. The compound was characterized by elemental, X-ray diffraction, and X-ray phase analysis. The salt is isostructural with the previously investigated compounds [M(NH₃)₅Cl][PtCl₄] (M = Ir, Rh, Ru, Co, Cr) and [CM(NH₃)₅Cl][PdBr₄] (M = Ir, Rh, Co). Crystallographic data: space group Pnma, a = 17.068(2) Å, b = 8.315(12) Å, c = 9.653(14) Å; V = 1370.0(3) Å³, Z = 4, d _calc = 2.903 g/cm³.

Keywords:	chromium palladium chloropentaammine bromine complexes X-ray phase analysis X-ray diffraction analysis crystal chemistry
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