Influence of isomorphous cation and anion substitution on optical spectra of cobalt alkylaminehalide crystals |
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Authors: | V B Kapustyanyk Yu M Korchak S A Sveleba V I Mokryi |
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Institution: | (1) I. Franko Lvov National University, 8 Cyril and Methodius Str., 290005 Lvov, Ukraine;(2) Lvov State Wood Technology University, Ukraine |
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Abstract: | Based on data of spectral investigations of crystals with the group A2CoCl4 (A=NH2(C2H5)
2
+
, N(C2H5)
4
+
, N(CH3)
4
+
) and N(C2H5)4]2CoCl2Br2, the identification of absorption bands corresponding to internal electron transitions in a Co2+ ion has been carried out. The values of the crystalline field force Dq for the above-indicated materials at room temperature
have been determined. The regularities of the change in the given parameter with change in the temperature and isomorphous
cation-anion substitution have been established. It is shown that substitution of chlorine ions by bromine ions in the N(C2H5)4]2CoCl2Br2 solid solution leads to the formation of distorted tetrahedral complexes CoCl2Br2.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 1, pp. 91–95, January–February, 2000. |
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Keywords: | tetrachlorometallate ferroelectric ferroelastic absorption band electron transition cation-anion substitution crystal field force |
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