| 二(顺丁烯二酸异丙酯酰氧基)-异丙氧基钕及其与甲基丙烯酸甲酯共聚物的研究 |
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| 引用本文： | 汪联辉,章文贡. 二(顺丁烯二酸异丙酯酰氧基)-异丙氧基钕及其与甲基丙烯酸甲酯共聚物的研究[J]. 高分子学报, 1997, 0(2) |
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| 作者姓名： | 汪联辉 章文贡 |
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| 作者单位： | 福建师范大学高分子研究所 |
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| 摘 要： | 用三异丙氧基钕与顺丁烯二酸酐反应合成含钕单体二（顺丁烯二酸异丙酯酰氧基） 异丙氧基钕，并与甲基丙烯酸甲酯（ＭＭＡ）共聚而制得含钕共聚物．用元素分析、ＩＲ、ＸＰＳ和ＳＥＭ对其结构进行表征，并研究了其热性能、光学性能和磁性．表明含钕共聚物是一种具有优异热稳定性、高透光率和大折光率，以及具有光选择吸收性和顺磁性的高分子材料
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| 关 键 词： | 稀土金属，含稀土聚合物，二（顺丁烯二酸异丙酯酰氧基）-异丙氧基钕 |
STUDY ON DI(ISOPROPYL MALEATE OYLOXYL) ISOPROPOXYL NEODYMIUM AND ITS COPOLYMER WITH METHYL METHACRYLATE |
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| WANG Lianhui,ZHANG Wengong. STUDY ON DI(ISOPROPYL MALEATE OYLOXYL) ISOPROPOXYL NEODYMIUM AND ITS COPOLYMER WITH METHYL METHACRYLATE[J]. Acta Polymerica Sinica, 1997, 0(2) |
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| Authors: | WANG Lianhui ZHANG Wengong |
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| Abstract: | Nd containing monomer,di(isopropyl maleate oyloxyl) isopropoxyl neodymium,is synthesized by the reaction of neodymium isopropoxide with maleic anhydride.Then Nd containing copolymer is prepared by the copolymerization of Nd containing monomer with MMA using AIBN as an initiator.Their structure are characterized by elemental analysis,IR,XPS,and SEM.Studies on the properties of Nd containing copolymer indicate that,in comparison with PMMA, it has excellent heat stability,higher transmittance,larger refractive index,characteristic selective light absorbability,and paramagnetism. |
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| Keywords: | Rare earth metal Rare earth metal containing polymer Di(isoproxyl maleate oyloxyl) isopropoxyl neodymium |
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