The Cu- and Zn-complex-catalyzed methanolysis of the chemical warfare nerve agents soman,sarin, and VX |
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Authors: | Nicoleta Petrea Răzvan Petre Andrada Pretorian Constantin Toader Vasile Şomoghi Florentina Neaţu Mihaela Florea Ştefan Neaţu |
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Affiliation: | 1. Scientific Centre for CBRN Defence and Ecology, 225 Oltenitei Road, 041309 Bucharest, Romania;2. S.C. Stimpex S.A., 46-48 Nicolae Teclu Street, 032368 Bucharest, Romania;3. National Institute of Materials Physics, 405 A Atomistilor Street, 077125 Magurele, Romania |
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Abstract: | The catalytic methanolysis of the chemical warfare nerve agents soman, sarin, and VX was investigated by using Cu or Zn complexes. Although VX withstood decontamination, the decomposition yield being around 96%, the soman and sarin deposited on different surfaces were almost fully destroyed under ambient conditions. The catalytic tests performed on a wide range of contaminated surfaces confirm the activity of the investigated catalytic systems, these complexes being suitable, from an economical point of view, for use in the formulation of a possible decomposition kit with military or civilian applicability. |
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Keywords: | Chemical warfare agents Catalytic decontamination Methanolysis Cu complex Zn complex Agents de guerre chimique Décontamination catalytique Méthanolyse Complexe du cuivre Complexe du zinc |
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