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The Cu- and Zn-complex-catalyzed methanolysis of the chemical warfare nerve agents soman,sarin, and VX
Authors:Nicoleta Petrea  Răzvan Petre  Andrada Pretorian  Constantin Toader  Vasile Şomoghi  Florentina Neaţu  Mihaela Florea  Ştefan Neaţu
Affiliation:1. Scientific Centre for CBRN Defence and Ecology, 225 Oltenitei Road, 041309 Bucharest, Romania;2. S.C. Stimpex S.A., 46-48 Nicolae Teclu Street, 032368 Bucharest, Romania;3. National Institute of Materials Physics, 405 A Atomistilor Street, 077125 Magurele, Romania
Abstract:The catalytic methanolysis of the chemical warfare nerve agents soman, sarin, and VX was investigated by using Cu or Zn complexes. Although VX withstood decontamination, the decomposition yield being around 96%, the soman and sarin deposited on different surfaces were almost fully destroyed under ambient conditions. The catalytic tests performed on a wide range of contaminated surfaces confirm the activity of the investigated catalytic systems, these complexes being suitable, from an economical point of view, for use in the formulation of a possible decomposition kit with military or civilian applicability.
Keywords:Chemical warfare agents  Catalytic decontamination  Methanolysis  Cu complex  Zn complex  Agents de guerre chimique  Décontamination catalytique  Méthanolyse  Complexe du cuivre  Complexe du zinc
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