Binuclear Copper(II) Complexes with Robsori-Type Ligands. Synthesis,characterization, crystal structure,and magnetic properties |
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Authors: | Peng Cheng Daizheng Liao Shiping Yan Jianzhong Cui Zonghui Jiang Genglin Wang Xinkan Yao Honggen Wang |
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Abstract: | Three binuclear copper(II) complexes, [Cu2(μ-L)(μ-N3)](ClO4)2′ 1-5 EtOH (1), [Cu2(μ-L)(μ-MeO)(ClO4)]-ClO4 - EtOH ( 2 ) and [Cu2(μ-L)(μ-C3H3N2)](ClO4)2 · 2H2O, ( 3 ) where L is the pentadentale bridging ligand derived from 5-(tert-butyl)-2-hydroxybenzene-1, 3-dicarbaldehyde bis(benzoylhydrazone) ( HL ) were synthesized and characterized. The crystal-structure determination of complex 2 provided the following crystal data: monoclinic, space group P21}/a, a = 11.412(2), b = 24.509(4), c = 14.833(4) Å, β = 104.41(2)°, K = 4018(3) Å3, Z = 4. The structure shows that the CuII ions are bridged by the endogenous phenolato O-atom and by an exogenous bridge CH3O?. The analysis of variable-temperature magnetic susceptibility data (4-300 K.) indicates that there is an antiferromagnetic interaction between the CuII ions in these complexes with an exchange parameter (2J) of ?119.1 cm?1 for complex 1 and ?361.8 cm?1 for complex 3 . The effect of some exogenous bridging ligands on magnetic coupling for this type of complex is suggested. |
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