|
|||||
|
|
Regio- and Stereocontrolled Nucleophilic Addition Reactions of An Unsymmetrically Disbustituted Butadiene η4-Molybdenum Cationic Complex |
|
| Authors: | Shang-Shing P Chou Hui-Tuo Sheng |
| Abstract: | The reactions of a new cationic complex, Cp(CO)2Mo(η4-2-methyl-3-SPh-C4H4)]+ PF?6 (3), with carbon, hydride, and nitrogen nucleophiles were found to give only the C-1 addition products in good yield. The X-ray crystal structures of two of the addition products 4a and 4e confirm the regio- and stereochemistry of the nucleophilic additions. |
| Keywords: | Butadiene molybdenum complexes Nucleophilic addition reactions |